Compact fuel cell type steam methane reformers with concentric annular. Catalytic steam reforming of methanol to produce hydrogen on. The steam reforming of methanol over a cuznoal2o3 catalyst has been investigated. Conventional twostep reforming topsoes conventional technology for producing syngas in methanol plants involves the socalled two step reforming concept 1 fig.
Steam reforming is the most efficient and popular way of producing hydrogen gas. A study of ethanol and methanol as a fuel for onboard hydrogen generation by steam reforming on copperbased. This chapter focuses mainly on the challenges of catalyst development for methanol steam reforming. Jul 30, 20 methanol reformers are large largest reformer has 960 tubes two to three times the size of an ammonia reformer many reformers in the range 600900 tubes why is this. The primary ways in which methane, is converted to hydrogen. Hydrogen production by steam reforming of ethanol over pt. Nonsyngas direct steam reforming of methanol to hydrogen and. A new palladiumbased catalyst for methanol steam reforming in. Methanol steam reforming msr reaction has been seen as a very attractive and promising process for hydrogen production and, according to the scientific literature on the argument, it can be described by the following chemical reactions. Review article covering developments in methanol steam reforming in the context of pem fuel cell power systems. Classical pemfc stack operates at 90 c while hightemperature pemfc stack operates at 250 c. Combined steam reforming and partial oxidation of methane to. A methanol reformer is a device used in chemical engineering, especially in the area of fuel cell technology, which can produce pure hydrogen gas and carbon dioxide by reacting a methanol and water steam mixture. The basic idea is that for example a methanol tank and a steam reforming unit would replace the bulky pressurized hydrogen tanks that would otherwise be necessary.
Deactivation of copper metal catalysts for methanol. Study on coupling model of methanol steam reforming and. Steam reforming of methanol for fuel cell grade hydrogen. Compact unit in combining both reaction and hydrogen purification with a. Pdf modeling methanol steam reforming for internal. Steam reforming of methane produces a mixture of co2, co, and h2. The main purpose of this technology is to hydrogen production. In the first part of the plant natural gas is converted into synthesis gas. Mechanistic kinetic models for steam reforming of concentrated crude. In methanol synthesis involving modern promoted cuznoal2 o3 catalysts neither poisoning nor coking is normally a significant source of deactivation. Pdf in the recent years, hydrogen has gained a considerable interest as an energy. Nov 27, 2012 a nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst at 150200 c.
Methanol steam reforming over exhydrotalcite cuznal. Mar 21, 2012 methanol might thus play a key role in the transition toward a future energy scenario, which has to be more and more independent from fossil sources. Methanol steam reforming for hydrogen generation via. Methanol has a low boiling point, a high hydrogencarbon ratio and no cc bonds, and can therefore be reformed at a relatively low temperature, reducing the risk of coke formation during the reaction.
Methanol steam reforming for fuel cell applications. A nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst. Study of different designs of methanol steam reformers. Autothermal reformers atrs combine some of the best features of steam reforming. Steam reforming and partial oxidation are the two basic types of fuel. Steam reforming of liquid hydrocarbons is seen as a potential way to provide fuel for fuel cells. Pdf progress in methanol steam reforming modelling via.
The reaction is very endothermic and typically occurs in a fixed bed reactor, heated by an open flame furnace with natural gas as the feedstock. Combined steam reforming and partial oxidation of methane to synthesis gas under electrical discharge korada supat and sumaeth chavadej the petroleum and petrochemical college, chulalongkorn university, bangkok 10330, thailand. Proven autothermal reforming technology for modern large. Methanol steam reforming in a dual bed membrane reactor for. The top countries of supplier is china, from which the percentage of methanol reforming supply is 95% respectively. Using 23wt% cu80zno20cnts as the catalyst, we obtained the hydrogen yield for steam reforming of methanol of 83% at 280c and near 100% at temperatures higher than 320c with 1. Methanol steam reforming for in situ hydrogen production for fuel cell applications has been studied mostly as a standalone process. Experiment and modeling article pdf available in international journal of hydrogen energy 3935 october 2014 with 379 reads. Review of small stationary reformers for hydrogen production. Parametric study of hydrogen production from ethanol steam. The goal of the reformer is to remove as much of the hydrogen h as possible from this molecule, while minimizing the emission of pollutants such as carbon monoxide co.
Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. Methanol steam reforming for hydrogen generation via conventional and membrane. Steam reforming sr of methanol has been extensively studied in recent years 17. All reforming is done in this reformer there is no secondary therefore choose the cheapest design and easiest to scale up therefore use top fired why. Methanol steam reforming for hydrogen production request pdf. A wide variety of methanol reforming options are available to you, there are 180 suppliers who sells methanol reforming on, mainly located in asia. A potential advantage of the membrane microreactor is the fact that both ethanol steam reforming and the separation of hydrogen by a permselective membrane occur in one single microdevice. Steam reforming of methanol for fuel cell applications. Hydrogen production by steam reforming of ethanol over ptceo 2 catalyst in electric field at low temperature.
Over cuzno catalysts prepared by a coprecipitation method, the steam reforming of methanol occurs with high selectivity regardless of composition of the catalyst and structure of the precursor aurichalcite, malachite, hydrozincite or their mixture. Development of a methanol reformer for fuel cell vehicles. From a technical point of view methanol is the ideal fuel, as it can easily be converted into hydrogen at reasonable temperatures methanol steam reforming and selective co methanation. An external reformer system consists of a combustor where a small fraction of fuel is burned and provides heat for the following steps, a vaporizer to heat and vaporize the fuel. Subjects covered include methanol background, use, and production, comparison to. An efficient technique for improving methanol yield using dual co 2. Methanol is considered an attractive raw material due to the high hydrogencarbon ratio 4. International journal of hydrogen energy 2015, 40 33, 1046310479. Steam methane reforming is the most common and economical way to make hydrogen. Methanol steam reforming for hydrogen generation via conventional.
The reaction yields carbon dioxide and hydrogen in the ratio of one to three, with small amounts of dimethyl. Methanol steam reforming also requires relatively low water to carbon molar ratio. There are a couple of types of steam reformers, one reforming methanol and the other reforming natural gas. The synthesis gas reacts to produce methanol in the second section, and methanol is purified to the desired purity in the tailend of the plant. Ethanol contains higher number of hydrogen per molecule as compared to water, methanol and methane. The wellknown steam reforming process usually used to extract hydrogen from methanol, called the methanol reformer, traditionally produces carbon.
Nonsyngas direct steam reforming of methanol to hydrogen. Srm is defined as steam reforming of methanol frequently. Dec 25, 2014 steam reforming of ethanol was carried out at 500 c over the ni catalysts prepared, which were compared to the total conversion and h 2 yield at the initial stage after 5 min and at the later stage after 200 min figure 2. Reformers for the production of hydrogen from methanol and. Final forms of the rate expressions for the overall reactions involved in the process of steam reforming of methanol can be expressed as. Aug 07, 1990 the production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800 to about 1,100 f. In both systems the methanol reformer operates at 250 c and steamtomethanol ratio of 1. The simulation results for steam reforming yields are in agreement with experimental data found in the literature. Advances in methanol production and utilization, with. Generally methanol reforming reaction occurs at comparatively lower temperature 200300c as compared to the temperature 800900c for gasoline reforming. Pdf hydrogen production by the catalytic steam reforming. Steam reforming of methanol is endothermic overall i. Kinetics, catalysis and mechanism of methane steam reforming.
At present, most of the worlds hydrogen is produced from natural gas 97 % ch4 by a process called steam reforming 38. Steam methane reforming smrbased methanol synthesis plants. In describing methanol steam reforming, we have limited our. Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. Where, where, the ratedetermining step chosen for both the methanol steam reforming reaction and the decomposition reaction was the dehydrogenation of adsorbed methoxy. Pdf methanol steam reforming for hydrogen generation via. Semipassive dmfcs represents a particular class able to combine. Pdf methanol steam reforming for hydrogen production. C2pt catalyst process technology by gerard b hawkins managing director 2. For a comparison, the catalytic performance of sm support was also measured. Methanol steam reformer high temperature pem fuel cell system.
Method of steam reforming methanol to hydrogen engelhard. The capital cost of large scale methanol plants is substantial. Additionally, the system with a classical pemfc stack uses a catalytic burner to supply the endothermal reforming process with sufficient heat. Mwcnts as a catalyst in oxysteam reforming of methanol. Developmentcommercialization status of methanol steam reformers. Hydrogen production by the catalytic steam reforming of methanol part 1. Micromachined methanol steam reforming system as a hydrogen supplier for portable proton exchange membrane fuel cells daeeun parka. Methanol steam reforming behavior of copper impregnated over ceo 2 zro 2 derived from a surfactant assisted coprecipitation route. In contrast, catalyst poisoning and coking have been observed in methanol decomposition and methanol steam reforming reactions. Atr combines substoichiometric combustion and catalytic steam reforming in one compact refractory lined reactor to produce synthesis gas for production of more than 10,000 mtpd of methanol. This might mitigate the distribution problems associated with hydrogen.
Micromachined methanol steam reforming system as a hydrogen. The process layout includes adiabatic prereforming 2, tubular reforming, and oxygenblown secondary reforming. During steam reforming of ethanol, catalyst plays a major role in the productivity and selectivity of generated gas. Cuznoal2o3 catalysts have been prepared via hydrotalcitelike hydroxycarbonate precursors and tested in the oxidative steam reforming of methanol mosr to produce hydrogen with poor co content. Modeling methanol steam reforming for internal combustion engine. Catalytic steam reforming of methanol to produce hydrogen. Stable hydrogen production from ethanol through steam. Methanol steam reforming for hydrogen production chemical. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. Jul 28, 20 steam reforming the basics of reforming 1. The steam reformer how fuel processors work howstuffworks. It also makes the steam reforming process of methanol energetically favorable.
264 936 452 1371 1439 348 1243 107 1023 938 1561 1237 1173 552 1049 576 391 1153 88 98 324 1516 710 511 516 327 99 1233 229 34 952 582 1305 104 180 845 564 1297 833 1449 399 1312 1126 633 551 977 691 872 183